You will need to use a progressive amount of force.
That valve is really welded on. I had to use significant torque to remove it. First tried a plumbers wrench, which started to mangle the brass fitting. Then used my hand and got the entire valve moving, only to leave the brass fitting still in the tank since it also threads into the valve body. Then back to the wrench and some more persuasion.
I replaced mine, details / pictures here:
https://www.airforums.com/forums/f44...ml#post2229785