This stuff is the greatest all-purpose sealant used thru-out the higher end of the RV industry. Almost every OEM that is building the $250,000+ bus-type RV, not to mention Airstream as well use this in liberal quantities. Sika, Ltd is doing a great job providing the RV industry with the best sealants available.
With reference to your roof vent, there are 2 ways to attack this:
1: as stated above, lay down a 'gasket' of butyl tape, press the vent in and pop-rivet the vent cover onto the roof. Then, use liberal amounts of a product called 'Dicor self-leveling sealant'. This stuff is also used by just about every RV OEM I have had the pleasure to work with. It not only sticks to just about every surface, but it 'self-levels' and lays itself down to create a very smooth surface finish.
2: Using the SikaFlex 221 (in grey of course) coat the entire under surface of the vent and then press it into place. Rivet as above and then run some SikaFlex over each rivet and around the edge. Use a plastic putty knife to smooth as desired. A virtually bomb-proof seal will result.
Just hope that you don't ever have to remove the vent in method#2, as it has practically become a permanent part of the roof after the 24hour cure time.
